Research in my laboratory provides tools for, and insights into two technologically important problems: energy conversion and drug design. Aqueous conversion of renewable fuel sources to hydrogen can be performed with transition metal and solid state catalysts. Such aqueous reforming generates hydrogen-rich fuel streams that are contaminated with carbon monoxide. We develop reforming catalysts that selectively oxidize CO, and fuel cell electrodes tolerant to CO.

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2011

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Unprecedented Directing Group Ability of Cyclophanes in Arene Fluorinations with Diaryliodonium Salts, Joseph W. Graskemper, Bijia Wang, Linlin Qin, Kiel D. Neumann, and Stephen G. DiMagno

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Ligand Fluorination to Optimize Preferential Oxidation of Carbon Monoxide by Water-Soluble Rhodium Porphyrins, Justin C. Biffinger, ShriHarsha Uppaluri, Haoran Sun, and Stephen G. DiMagno

2010

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Fluoride-promoted ligand exchange in diaryliodonium salts, Bijia Wang, Ronald Cerny, ShriHarsha Uppaluri, Jayson J. Kempinger, and Stephen G. DiMagno

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Regiospecific Reductive Elimination from Diaryliodonium Salts, Bijia Wang, Joseph W. Graskemper, Linlin Qin, and Stephen G. DiMagno