Published Research - Department of Chemistry

 

Date of this Version

2014

Citation

J Am Chem Soc. 2014 Apr 23; 136(16): 5821–5823

Comments

Copyright © 2014 American Chemical Society

Abstract

The intramolecular reaction of dialkyl peroxides with carbanions, generated via chemoselective metal-heteroatom exchange or deprotonation, provides a new approach to cyclic ethers. Applied in tandem with C–C bond formation, the strategy enables a one-step annelation to form oxaospirocycles.

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