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The purpose of this study is to determine the effect of library services quality on achievement motivation associated with the learning achievement of Universitas Pendidikan Ganesha (UNDIKSHA) student. This research is conducted in Undiksha students using ex-post facto method. The sampling is done through random sampling method with 350 students. The data on library services quality and achievement motivation are collected using questionnaire. The data are analyzed using structural equation modeling (SEM). The research results show that a) Library services quality has an influence towards achievement motivation, with probability value of 0.034 (p<0.05), b) Library services quality has no influence towards learning achievement, with probability value of 0.585 (p>0.05), c) Achievement Motivation has an influence towards learning achievement with probability value of 0.026 (p<0.05), d) Achievement motivation fully mediated the effect of library quality towards learning achievement.