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This paper explained the influence of technological readiness on adoption of artificial intelligence technology, using data collected through Google form from 52 librarians in Nigeria. The study adopted descriptive survey research design and adapted the Technological Readiness Index 2.0 to design structured questionnaire on level of technological readiness among librarians in Nigeria. In addition, data was collected on demographic factors and prevalent artificial intelligent technologies adopted by the librarians. Findings reveal that Google Assistant is the prevalent artificial intelligence technology adopted by the librarians in Nigeria. Also, the librarians agreed more on the motivating factors than inhibiting factors for level of librarians’ technological readiness in Nigeria. However, findings from the study indicate that there is no significant relationship between technological readiness and adoption of artificial intelligence among librarians in Nigeria. Hence, the study suggests that other factors could contribute to the adoption of artificial intelligence among librarians in Nigeria.