Chemical and Biomolecular Research Papers -- Faculty Authors Series

 

Ravi Saraf Publications

Document Type

Article

Date of this Version

February 2003

Comments

Published by American Institute of Physics. Appl. Phys. Lett. Vol. 82, No. 6, 10 February 2003. © 2003 American Institute of Physics. Permission to use. http://apl.aip.org/.

Abstract

The possibility of using self-assembled films of block polymers as templates to fabricate nanoscale structures for devices has attracted great attention towards this class of material. Self-assembly of a block copolymer can be directed by using an electric field to orient features (i.e., ~10-nm-diam cylinders) parallel to the electric field, making the material more attractive as a nanoscale lithography mask. In this letter we describe an approach to influence the electric field orientation phenomena by interfacial effects. As a result, the 15-nm-diam polystyrene cylinders of the polystyrene–polyisoprene–polystyrene triblock copolymer orient perpendicular to the electric field. The described approach along with the previous method can produce a directed self-assembly to fabricate complex nanoscale structures with orthogonally oriented nanoscale width lines.

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