Mechanical & Materials Engineering, Department of

 

ORCID IDs

http://orcid.org/0000-0002-9810-2448

http://orcid.org/0000-0002-5415-1686

http://orcid.org/0000-0002-7223-2324

http://orcid.org/0000-0002-5544-590X

http://orcid.org/0000-0002-0509-8778

Date of this Version

2020

Citation

NATURE COMMUNICATIONS | (2020)11:2215 | https://doi.org/10.1038/s41467-020-16075-1 | www.nature.com/naturecommunications

Comments

The Author(s) 2020

Abstract

Grain boundaries have been established to impact charge transport, recombination and thus the power conversion efficiency of metal halide perovskite thin film solar cells. As a special category of grain boundaries, ferroelastic twin boundaries have been recently discovered to exist in both CH3NH3PbI3 thin films and single crystals. However, their impact on the carrier transport and recombination in perovskites remains unexplored. Here, using the scanning photocurrent microscopy, we find that twin boundaries have negligible influence on the carrier transport across them. Photoluminescence (PL) imaging and the spatial-resolved PL intensity and lifetime scanning confirm the electronically benign nature of the twin boundaries, in striking contrast to regular grain boundaries which block the carrier transport and behave as the non-radiative recombination centers. Finally, the twin-boundary areas are found still easier to degrade than grain interior.

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