Research Papers in Physics and Astronomy

 

Title

Comparison of the electronic structure of two polymers with strong dipole ordering

Document Type

Article

Date of this Version

March 2006

Comments

Published in Journal of Physics: Condensed Matter 18:13 (5 April 2006), pp. L155-L161. doi:10.1088/0953-8984/18/13/L01 http://www.iop.org/EJ/journal/JPhysCM © 2006 IOP Publishing Ltd. Used by permission.

Abstract

Two different polymers, with large local electric dipoles, are compared: copolymers of polyvinylidene fluoride with trifluoroethylene [P(VDF-TrFE, 70%:30%)] and polymethylvinylidenecyanide (PMVC). While the different local point group symmetries play a key role, both crystalline polymers exhibit intra-molecular band structure, though the Brillouin zone critical points differ.