Date of this Version
Prepared by Pennsylvania State University for Pacific Northwest Laboratory, (1995)
This report presents the development of a mixed chemical Kinetic and Equilibrium MODel (KEMOD), in which every chemical species can be treated either as a equilibrium-controlled or as a kinetically controlled reaction. The reaction processes include aqueous complexation, adsorption/ desorption, ion exchange, precipitation/dissolution, oxidation/reduction, and acid/base reactions. Further development and modification of KEMOD can be made in: (1) inclusion of species switching solution algorithms, (2) incorporation of the effect of temperature and pressure on equilibrium and rate constants, and (3) extension to high ionic strength.