Date of this Version
Journal of Nanomaterials Volume 2015, Article ID 264037, 8 pages
Environmentally benign and easily recoverable magnetite nanoparticles (Fe3O4 NPs) were demonstrated to catalyze the one-pot conversion of cellobiose, a glucose disaccharide, to 5-hydroxymethylfurfural (5-HMF).Theconversion was achieved in water under hydrothermal conditions.The catalytic activity of Fe3O4 NPs surpassed those of iron (II) and iron (III) chlorides in this reaction. Optimized cellobiose conversion reactions catalyzed with Fe3O4 NPs gave the highest 5-HMF yields of 23.4 ± 0.6% at 160∘C for 24 hours. After three reuses, the Fe3O4 NP catalyst retained its catalytic activity with similar 5-HMF yields, demonstrating the recyclability of this eco-friendly catalyst in water.