Department of Chemistry

 

Document Type

Article

Date of this Version

3-2011

Comments

Published in Journal of the American Chemical Society 133:16 (2011), pp. 6170–6173; doi: 10.1021/ja201826r Copyright © 2011 American Chemical Society. Used by permission.

Abstract

Two {110}-faceted gold nanostructures—rhombic dodecahedra and obtuse triangular bipyramids—have been synthesized via a Ag-assisted, seed-mediated growth method. The combination of a Cl−-containing surfactant with a low concentration of Ag+ plays a role in the stabilization of the {110} facets. To the best of our knowledge, this is the first reported synthesis of a {110}-faceted bipyramid structure.

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