Department of Chemistry
Date of this Version
May 2005
Abstract
Neighboring iodo-, alkoxy-, acetoxy- and silyl groups impart useful levels of diastereoselection in the Lewis acid-mediated allylation of monoperoxyacetals. Although monoperoxyacetals are found to be considerably less reactive than corresponding nonperoxidic acetals, similar stereochemical trends are observed in the two series.
Comments
Published in Tetrahedron 61:19 (9 May 2005), pp. 4657–4670. Copyright © 2005 Elsevier Ltd. Used by permission. doi:10.1016/j.tet.2005.02.071 http://www.sciencedirect.com/science/journal/00404020