Published Research - Department of Chemistry

 

Date of this Version

2014

Citation

Org. Lett. 2014, 16, 5298−5300

Comments

Open Access licensed. Used by permission.

Abstract

A series of unnatural amino acids functionalized with sterically shielded pyrroline nitroxides were synthesized. Their reduction by ascorbate/glutathione indicates that Lcysteine functionalized with gem-diethylpyrroline nitroxide is reduced at the slowest rate and is comparable to that measured for the most resistant to reduction pyrroline and pyrrolidine nitroxides.

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