ƴ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes

Authors

• Sean M Smith, University of Nebraska-Lincoln
• Gia L. Hoang, University of Nebraska-LincolnFollow
• Rhitankar Pal, University of Nebraska-Lincoln
• Mohammad O. Bani Khaled, University of Nebraska-Lincoln
• Liberty S. W. Pelter, Purdue University Calumet
• Xiao Cheng Zeng, University of Nebraska-LincolnFollow
• James M. Takacs, University of Nebraska-LincolnFollow

Document Type

Article

Date of this Version

2012

Citation

Chem. Commun., 2012, 48, 12180–12182

Comments

Used by permission.

Abstract

Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford ƴ

-dioxaborato amides and esters in high enantiomeric purity (90–95% ee).