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E-learning is one of the emerging issues in LIS education in Nigeria and students in the LIS profession have been adopting some of these technologies in enhancing their professional skills. E-learning is becoming increasingly prominent in higher education, with Universities increasing provision and more students signing up. In University of Nigeria, E-learning is at its infant stage, though a good number of the students have been introduced to it, and some of the students have already started using it for some courses. This paper examines factors that predict UNN LIS students’ intention to adopt e-learning. Understanding the nature of these factors may assist Nigerian Universities in promoting the use of Information and Communication Technology (ICT) in teaching and learning. Data was collected through a survey of 50 LIS students at the University of Nigeria, Nsukka. The technology adoption model is utilized in this study. Two more independent variables are added to the original model, namely, the pressure to act and resource availability. The results show that there are five factors that can be used in modeling students’ intention to adopt e-learning. These factors are attitudes toward e-learning, perceived usefulness of e-learning, perceived ease of e-learning use, pressure to use e-learning, and the availability of resources needed to use e-learning.