The study was conducted to show Library Information Services Seeking Behaviour among Students of Adeyemi College of Education, Ondo, Nigeria The research design for the study was descriptive survey research design. The population comprises all the students (Degree Students) in Adeyemi College of Education, Ondo. 100 undergraduates were sampled. Random sampling technique was also used for the study. Therefore the sample size of the study was one hundred. A 6-section research instrument adapted by the researcher was used in the study. The researchers collected the data through face-to-face administration of questionnaire. The study shows that the students’ level of awareness about the library services in the college library of Adeyemi College of Education, Ondo is high. However, it can be inferred that the rate of satisfaction with the library services in the college library of ACE, Ondo is low.