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The structure of La0.65Pb0.35MnO3 has been studied by neutron powder diffraction. From the temperature dependence of the lattice parameters, we observe that La0.65Pb0.35MnO3 remains single phase in the temperature interval from 25 to 400 K, with a rhombohedral (R3c) structure. The collinear Mn spins suffer a thermally driven reorientation transition close to the Curie temperature, as obtained from powder samples (using neutron diffraction) and from thin films [using ferromagnetic resonance (FMR)]. The reorientation transition may indicate the presence of local Jahn–Teller (JT) lattice distortions, which are prevented from developing with long-range order in the R3c crystal structure.