Research Papers in Physics and Astronomy

 

Date of this Version

2003

Document Type

Article

Citation

SCIENCE VOL 300 23 MAY 2003

Comments

Used by permission.

Abstract

Electric deflections of gas-phase, cryogenically cooled, neutral niobium clusters [NbN; number of atoms (N) = 2 to 150, temperature (T) = 20 to 300 kelvin], measured in molecular beams, show that cold clusters may attain an anomalous component with very large electric dipole moments. In contrast, room-temperature measurements show normal metallic polarizabilities. Characteristic energies kBTG(N) [Boltzmann constant kB times a transition temperature TG(N)] are identified, below which the ferroelectric-like state develops. Generally, TG decreases [110 > TG(N) > 10K] as N increases, with pronounced even-odd alternations for N > 38. This new state of metallic matter may be related to bulk superconductivity.

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