Chemical and Biomolecular Engineering Research and Publications
Spontaneous planarization of nanoscale phase separated thin film
Document Type Article
Originally Published in Applied Physics Letters, American Institute of Physics on !0 june 2002. DOI: 10.1063/1.1481187 This article can be viewed at: http://apl.aip.org/
Abstract
Structure of complex fluid at mesoscales is influenced by interfacial effects. We describe the dynamic response in such films to sudden change in interfacial tension. In a self-assembled block copolymer film, the monolayer of 15 nm diam cylindrical discrete phases close to the surface commence to sink at an average rate of 0.16 nm/day in response to the interfacial tension change. Surprisingly, this spontaneous planarization occurs, even though the cylinders are covalently stitched to the matrix. A simple model explains the observed behavior. The observation may lead to approaches to tailor the structure of mesoscale thin films of complex fluids for long-range order that are desirable for nanoscale device fabrication.