Mechanical and Materials Engineering, Department of
Department of Mechanical and Materials Engineering: Faculty Publications
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Document Type
Article
Date of this Version
11-15-2003
Abstract
The cation distribution in the spinel ferrite system NixMn1-γ-xFe2+γO4 (x = 0, 0.25, 0.5, 0.75 and γ = 0.137) has been calculated analytically in complete form as a function of thermodynamic parameters. A generalized theoretical framework based on the O’Neill–Navrotsky model and Newton methods was used to solve a multicomponent system for up to 10 cation species. The relationship between the cation distribution and composition is given. The results are shown to agree with the available experimental results.
Comments
Published in Journal of Solid State Chemistry 176 (2003): 279–283. Copyright 2003, Academic Press/Elsevier. doi: 10.1016/S0022-4596(03)00382-7 Used by permission.