An organosilane self-assembled monolayer incorporated into polymer solar cells enabling interfacial coherence to improve charge transport

Authors

Zhiqi Li, Jilin University
Xinyuan Zhang, Jilin University
Zhihui Zhang, Jilin University
Shujun Li, Jilin University
Chunyu Liu, Jilin University
Liang Shen, Jilin University
Wenbin Guo, Jilin UniversityFollow
Shengping Ruan, Jilin UniversityFollow

Date of this Version

2016

Citation

Phys. Chem. Chem. Phys., 2016, 18, 16005--16012

DOI: 10.1039/c6cp02722a

Comments

© the Owner Societies 2016

Abstract

The reproducible silylation of titanium oxide (TiO₂) with small molecular (dichloromethyl) dimethylchlorosilane (DCS) as the cathode buffer layer was developed to improve electron extraction. Through incorporating the DCS capping layer into polymer solar cells (PSCs), the interfacial coherence of devices could be enhanced, leading to a shift in nanocrystallite size and a smaller internal charge transport resistance. Furthermore, a TiO₂/DCS combined interfacial layer could serve as both an exciton dissociation center and a charge transfer channel, which results in a reduction in the energy barrier and electron loss, improving hole-blocking and surface-state passivation in the TiO₂ interfacial layer. The Kelvin probe measurements demonstrate that the employment of the DCS nanolayer decreases conduction band energy of TiO₂ via forming a dipole layer at the interface of TiO₂ and the DCS nanolayer, which tunes the work-function of the device and ulteriorly enhances charge carrier transfer between the electrode and the active layer. As a result, the photocurrent and the fill factor of the PSCs are both increased, resulting in an increased power conversion efficiency (PCE) of 6.959%.