Water absorption and dielectric changes in crystalline poly(vinylidene fluoride-trifluoroethylene) copolymer films

Authors

P.A. Jacobson, University of Nebraska-Lincoln
Luis G. Rosa, University of Nebraska-LincolnFollow
Christina M. Othon, University of Nebraska-LincolnFollow
Kristin L. Kraemer, University of Nebraska-LincolnFollow
A.V. Sorokin, University of Nebraska-Lincoln
Stephen Ducharme, University of Nebraska-LincolnFollow
Peter A. Dowben, University of Nebraska-LincolnFollow

Date of this Version

1-5-2004

Comments

Published Applied Physics Letters 84 (2004) 88-90. Permission to use.

Abstract

Crystalline Langmuir–Blodgett copolymer films of vinylidene fluoride with trifluoroethylene (70%:30% and 80%:20%) absorb water. Water absorption is accompanied by film swelling, as indicated by an increase in lattice spacing, sometimes by as much as 5%. This water absorption, between 0 and 40 °C, is a result of intercalation or occupation of interstitial sites between the layers of the film, not just water molecules filling voids and defect sites alone. An increase in the film capacitance is observed, although the polymer chains retain all trans configuration of the ferroelectric phase. © 2004 American Institute of Physics.