Hexagonal Rare-earth Manganites as Promising Photovoltaics and Light Polarizers

Authors

Xin Huang, Southeast University, China
Tula R. Paudel, University of Nebraska-LincolnFollow
Shuai Dong, Southeast University, ChinaFollow
Evgeny Y. Tsymbal, University of Nebraska - LincolnFollow

ORCID IDs

Tsymbal http://orcid.org/0000-0002-6728-5532

Paudel https://orcid.org/0000-0002-9952-9435

Document Type

Article

Date of this Version

12-9-2015

Citation

Physical Review B (2015) 92: 125201

doi: 10.1103/PhysRevB.92.125201

Comments

Copyright 2015, American Physical Society. Used by permission

Abstract

Ferroelectric materials possess a spontaneous electric polarization and may be utilized in various technological applications ranging from nonvolatile memories to solar cells and light polarizers. Recently, hexagonal rareearth manganites, h-RMnO₃ (R is a rare-earth ion), have attracted considerable interest due to their intricate multiferroic properties and improper ferroelectricity characterized by a sizable remnant polarization and high Curie temperature. Here we demonstrate that these compounds can serve as very efficient photovoltaic materials and, in addition, possess remarkable optical anisotropy properties. Using first-principles methods based on density functional theory and considering h-TbMnO₃ as a representative manganite, we predict a strong light absorption of this material in the solar spectrum range, resulting in a maximum light-to-electricity energy conversion efficiency of up to 33%. We also predict an extraordinary optical linear dichroism and linear birefringence properties of h-TbMnO₃ in a broad range of optical frequencies. These results uncover the unexplored potential of hexagonal rare-earth manganites to serve as photovoltaics in solar cells and as absorptive and birefringent light polarizers.