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This paper has focused on transformation of bibliographic data to linked open data (LOD) as RDF(Resource Description Framework) triple model with integration of external resources. Library & Information centres and knowledge centres deal with various types of databases like bibliographic databases, full text databases, archival databases, statistical databases, CD/DVD ROM databases and more. Presently, web technology changes storing, processing, and disseminating services rapidly. The semantic web technology is an advance technology of web platform which provides structured data on web for describing and retrieving by the organization or institutions. It may provide more information from other external resources to the users. The main objective of this paper is transformation of library bibliographic data, based on MARC21, to RDF triple format as LOD with enrichment of external LOD dataset. External resources like OpenLibrary, VIAF, Wikidata, DBpedia, GeoNames etc. We have proposed a Workflow model (Figure-1) to visualize details steps, activities, components for transforming bibliographic data to LOD dataset. The methodology of this work includes the various methods and steps for conducting such research work. Here we have used an open source tool OpenRefine (version 3.2), formally it is known as GoogleRefine. The OpenRefine tool is used for managing and organizing the messy data with different attribute like row-column manipulation, reconciliation manipulation, different format manipulation like XML, JSON, N-Triple, RDF etc. The OpenRefine tool has played the various roles for the research work such as insertion of URI column, link generation, reconciliation data for external sources, conversion of source format to RDF format etc. After conversion of whole bibliographic data into RDF triple format as considerable LOD dataset. At the production page we may find a RDF file of bibliographic data. This LOD dataset may further be used by the organizations or institutions for their advanced bibliographic service.